Effect of Biochar as Reductant on Magnetizing-roasting Behavior of Pyrite Cinder

The effect of biochar substituted for anthracite as reductant on magnetizing-roasting pyrite cinder was investigated.The key of magnetizing-roasting is the gasification reaction between reductants and CO2.Since biochar could react with CO2 more rapidly at lower temperature,the reactivity of biochar is better than that of anthracite.The gasification of biochar could produce reducing condition ofφCO/(φCO+φCO2)about 10%-20% between 700-800 ℃,which is in accord with the atmosphere and temperature of Fe2O3 reduction.So it is beneficial to the reduction of iron mineral of pyrite cinder.Compared with anthracite,biochar could decrease the roasting temperature from825 to 750 ℃ and roasting time from 20 to 15min,which shows that a better effect of magnetization could be obtained in the condition of lower temperature and shorter time.Using biochar as reductant,iron concentrate extracted from pyrite cinder as about 64%iron grade could be produced,and the recovery is over 90% under the condition of above 90% grinding particle less than 0.045 mm and magnetic intensity of 0.124-0.194 T.     

Application of Vis–NIR hyperspectral imaging in classification between fresh and frozen-thawed pork Longissimus Dorsi muscles

Fresh and frozen-thawed (F-T) pork meats were classified by Vis–NIR hyperspectral imaging. Eight optimal wavelengths (624, 673, 460, 588, 583, 448, 552 and 609 nm) were selected by successive projections algorithm (SPA). The first three principal components (PCs) obtained by principal component analysis (PCA) accounted for over 99.98% of variance. Gray-level-gradient co-occurrence matrix (GLGCM) was applied to extract 45 textural features from the PC images. The correct classification rate (CCR) was employed to evaluate the performance of the partial least squares-discriminate analysis (PLS-DA) models, by using (A) the reflected spectra at full wavelengths and (B) those at the optimal wavelengths, (C) the extracted textures based on the PC images, and (D) the fused variables combining spectra at the optimal wavelengths and textures. The results showed that the best CCR of 97.73% was achieved by applying (D), confirming the high potential of textures for fresh and F-T meat discrimination.     

The impact of inoculum source,inoculum to substrate ratio and sample preservation on methane potential from different substrates

Batch experiments were conducted to evaluate the impact of inoculum sources, inoculum to substrate (IS) ratio and storage conditions on the potential and production rate of methane (CH₄) from different substrates: wheat straw, whole crop maize, cattle manure, grass and cellulose.The results of the test with four inocula and four substrates indicated that inoculum source could have a significant impact on both CH₄ potential (BMP) and the kinetics parameters of different substrates. The two inocula showing the highest BMP and production rates in each period were those coming from a feeding with more than 70% of animal manure under thermophilic conditions. The impact of the IS ratio in the range 0.25–2.5, in terms of g volatile solids (VS) substrate/g VS inoculum, depended on substrate type. Maize silage was more affected to changes in the IS ratio than wheat straw. The optimal IS ratio range for maize was 1.0–1.5, however, a wider IS range can be used in wheat straw (0.5–2.5). The impact of freezing and drying depended on biomass type. Freezing, drying and ensiling of grass increased the CH₄ yield compared to fresh grass. Drying of maize had no impact while freezing reduced the CH₄ potential. Drying and freezing had no impact on straw.     

Decay Rate Kinetics of Ozone Gas in Rice Grains

The present study was carried out to evaluate the effects of ozone on rice grains for the following three conditions: saturation time, decay rate, and half-life of ozone. Experiments were performed in different bed thicknesses (5 and 10 cm) and moisture content (11.4 and 14.2% wb) at atmospheric conditions. The lowest saturation time of ozone was 119 min, with the concentration of 516 ppm for rice grains ozonated at 5-cm bed thickness with 11.4% (wb) moisture content. The decay rate kinetics of ozone obtained were consistent with a first-order model. Regarding the half-life of ozone, the lowest value obtained was 6.78 min for rice grains ozonated at 10-cm bed thickness with 14.2% (wb) moisture content.     

Effect of Solute Elements and Cooling Rate on Strain in Brittle Temperature Range of Continuously Cast Strand

A micro-segregation model of solute elements in mushy zone withδ/γtransformation during solidification was established based on the regular hexagon transverse cross section of dendrite shape proposed by finite difference method under the non-equilibrium solidification condition.The model was used to calculate the non-equilibrium pseudo binary Fe-C phase diagram and the strain of steels induced by variation of temperature in brittle temperature range.On the basis of the phase diagram and the strain,the strain curve in brittle temperature range as a function of carbon content for continuously cast strand was introduced and obtained.Solute elements change the position of the strain curve.And cooling rate changes the position and the shape of the strain curve.The comprehensive formula of the strain as functions of solute elements and cooling rate in brittle temperature range has been obtained by nonlinear fitting program.     

大型球磨机订购（制造）设计联络中零部件结构优化的探讨

针对大型球磨机使用中存在的问题，对球磨机主要零部件结构缺陷进行分析并提出解决方案。通过设计联络，提前对球磨机主要零部件结构进行优化，消除设备缺陷。大型球磨机设计联络中对主要零部件结构进行优化，对提高球磨机的运转率有着事半功倍的作用。     

Relations between asphaltene content,viscosity reduction rate of heavy oil and ultrasonic parameters

Ultrasonic treatment could decrease the viscosity of heavy oil and previous study on had focused on one heavy oil sample and involved less on the influence of asphaltene content. This study examined the effect of asphaltene content on viscosity reduction rate by ultrasonication. A comparison on samples with various asphaltene content and vibration parameter was made. The results showed that the optimal vibration frequency might decrease as the asphaltene content increased, whereas the optimal vibration intensity and the optimal treatment time were suggested to be enlarged. A semi-quantitative correlation was matched, which helped for numerical simulation about ultrasonic treatment.     

Experimental study on combustion stability and performance of hydrogen-enriched compressed natural gas of a free-piston linear generator

Free Piston linear Generator (FPLG) engine fueled by compressed natural gas (CNG) has recently gained increased research attention. However, due to the low-velocity burning and poor lean limit of CNG fuel, the FPLG engine combustion stability, performance, and efficiency are still low. Hydrogen has a greater burning velocity with wider flame limits that could extend the lean burn limits and combustion characteristics of CNG. This paper compares pure CNG and 10% hydrogen-enriched CNG at various ignition speeds (0.6 ms, 0.8 m/s, and 1 m/s), injection positions (0 mm, 5 mm, 10 mm and 15 mm), and lambda ratios (0.9, 1.4 and 1.7) on the combustion characteristics, performance, and conversion efficiency are duly discussed. The findings show that the FPLG combustion stability limits increase with the hydrogen addition into the CNG. The CNG in-cylinder pressure increases significantly when the injection position is advanced, whereas the hydrogen addition reduces the influence of the injection position. The heat release rate increases by 15.62% and 23.72% with hydrogen addition, corresponding to the advanced and retarded injection positions. Consequently, the hydrogen addition increases the power RMS to 209.21 W and 232.64 W with an increment of 3.46% and 3.13%, respectively. Conclusively, the hydrogen addition into the CNG evidently shortens the combustion duration while improving the heat release rate, combustion stability, power RMS, Cycle-to-Cycle variation, and conversion efficiency.     

Comparison of thermophilic and hyperthermophilic dark fermentation with subsequent mesophilic methanogenesis in expanded granular sludge bed reactors

Herein, dark fermentation (DF, V = 5.5 L) and subsequent mesophilic methanogenesis (V = 43.5 L) are run as expanded granular sludge bed reactors (EGSB) at thermophilic (υDF = 60 °C) and hyperthermophilic (υDF = 80 °C) temperatures. A synthetic glucose wastewater is run with a 22.5 g/L chemical oxygen demand (COD) and 48–9 h hydraulic retention times (HRTs), giving organic loading rates (OLRs) of 11–60 g COD/L/d for DF. The maximum hydrogen production rate (HPR) is HPR = 3.0 m³/m³/d for HRT = 9 h with a 50 L/kg COD hydrogen yield (HY) and 40 vol% H₂. Methane production rate (MPR) reaches MPR = 2.6 m³/m³/d with 70 vol% CH₄ at HRT = 2.8 d. The highest H₂ yields are HY = 180 L/kg COD with 53 vol% H₂ (thermophilic, HRT = 48 h). Hyperthermophilic temperatures led to lower HPRs (0.7 m³/m³/d) and MPRs (1.6 m³/m³/d). 53% of Thermoanaerobacterium thermosaccharolyticum as an H₂ producer are found. Discoloration of granular sludge from black to white and granule stability was observed in DF.     

Deep-blue thermally activated delayed fluorescence emitter with a very high fluorescence rate

Conventional thermally activated delayed fluorescence (TADF) molecules achieve small energy differences between the lowest singlet and triplet excited states (ΔE_ST) by enhancing the intramolecular charge transfer, which inevitably leads to a wide emission spectrum and low fluorescence rate. Here, we prepared a deep blue TADF molecule via a small ΔE_ST pyridine-phenol fluoroboron complex as the acceptor. The small ΔE_ST is maintained when carbazole donors are attached to the 4-position of the phenyl rings in the fluoroboron complex. Benefiting from the strong electron coupling between the donor (D) and acceptor (A) moieties, the compound Cz-4-BF exhibits a high fluorescence rate of 4.8 × 10⁸ s⁻¹ and a small D-A dihedral angle change in the excited state. Consequently, a photoluminescence (PL) quantum yield of nearly 100% and a PL spectrum with full-width at half-maximum (FWHM) < 60 nm were obtained in solution and low-concentration doped films. A TADF-sensitized fluorescence (TSF) device containing Cz-4-BF achieves an external quantum efficiency of 21%, which is higher than the devices employing classical fluorescent emitters and multiple resonance-type TADF emitters. The Cz-4-BF-based TSF device shows significantly improved color coordinates of (0.14, 0.10) versus a control device without Cz-4-BF.